Bis[μ-1,2-diphenyl-N,N′-bis(di-2-pyridylmethyleneamino)ethane-1,2-diimine]disilver(I) bis(hexafluoridophosphate) acetonitrile disolvate
oleh: Lin Bao, Xiaoqiang Gan, Ping Chen, Tao Xiao, Qiaozhen Sun
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2009-12-01 |
Deskripsi
In the centrosymmetric dinuclear title compound, [Ag2(C36H26N8)2](PF6)2·2C2H3N, the Ag+ ion is bound to four N atoms from two 1,2-diphenyl-N,N′-bis(di-2-pyridylmethyleneamino)ethane-1,2-diimine ligands in a distorted tetrahedral geometry. The ligand adopts a twist conformation, coordinating two metal centers by three pyridyl N atoms and one imine N atom and spanning two Ag+ ions, resulting in the formation of a helical dimeric structure.