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The high dependence on and high cost of lithium has led to a search for alternative materials. Aluminum ion batteries (AIBs) have gained interest due to their abundance, low cost, and high capacity. However, the use of the expensive 1-ethyl-3-methylimidazolium chloride (EMIC) electrolyte in AIBs curtails its wide application. Recently, high-temperature batteries have also gained much attention owing to their high demand by industries. Herein, we introduce cost-effective 1T molybdenum sulfide grown on SP-1 graphite powder (1T-MoS₂/SP-1) as a cathode material for high-temperature AIBs using the AlCl₃-urea eutectic electrolyte (1T-MoS₂/SP-1–urea system). The AIB using the 1T-MoS₂/SP-1–urea system exhibited a capacity as high as 200 mAh/g with high efficiency of 99% over 100 cycles at 60 °C when cycled at the rate of 100 mA/g. However, the AIB displayed a capacity of 105 mAh/g when cycled at room temperature. The enhanced performance of the 1T-MoS₂/SP-1–urea system is attributed to reduced viscosity of the AlCl₃-urea eutectic electrolyte at higher temperatures with high compatibility of 1T-MoS₂ with SP-1. Moreover, the electrocatalytic lithiation of 1T-MoS₂ and its effect on the hydrogen evolution reaction were also investigated. We believe that our work can act as a beacon for finding alternative, cost-effective, and high-temperature batteries.