Bis[1,2-bis(dimethylphosphino)ethane-κ2P,P′]rhodium(I) dichlorido[(1,2,5,6-η)-1,5-cyclooctadiene]rhodium(I)
oleh: Michael Block, Santiago Gómez-Ruiz, Dirk Steinborn
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2008-11-01 |
Deskripsi
In the title complex, [Rh(C6H16P2)2][RhCl2(C8H12)], the asymmetric unit contains two [Rh(dmpe)2] [dmpe = 1,2-bis(dimethylphosphino)ethane] half-cations, lying on inversion centers, and an [RhCl2(cod)]− (cod = 1,5-cyclooctadiene) anion, wherein Rh is coordinated by two chloride ligands and two olefinic π-bonds of the cyclooctadiene ligand. The Rh atoms in the cations and anion exhibit square-planar coordination and are separated without any unusual interactions.