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Ferroelectric and Electrical Properties Optimization of Mg-doped BiFeO<sub>3</sub> Flexible Multiferroic Films
oleh: Der-Yuh Lin, Hone-Zern Chen, Ming-Cheng Kao, Pei-Li Zhang
| Format: | Article |
|---|---|
| Diterbitkan: | MDPI AG 2020-07-01 |
Deskripsi
Bi<sub>1-x</sub>Mg<sub>x</sub>FeO<sub>3</sub> (BMFO, x = 0, 0.02, 0.04, 0.06 and 0.08) multiferroic films were directly synthesized on flexible stainless steel (FSS), save the bottom electrode process, by means of sol–gel spin-coating technology. The effects of different bending conditions on ferroelectric, dielectric and leakage-current properties of BMFO films were investigated. The leakage-current densities of BiFeO<sub>3</sub> (BFO, x = 0) and BMFO (x = 0.06) films were 5.86 × 10<sup>−4</sup> and 3.73 × 10<sup>−7</sup> A/cm<sup>2</sup>, which shows that the BMFO (x = 0.06) has more than three orders of magnitude lower than that of BFO film. The residual polarization (2 Pr) can be enhanced from 120 to 140 μC/cm<sup>2</sup>. The proper doping of Mg in BiFeO<sub>3</sub> film could provide an effective method for reducing the leakage-current values as well as boosting the ferroelectric properties. In this study, the leakage-current mechanism of low electric field and high electric field of BMFO film is analyzed and established. In addition, the flexible BMFO film maintains practical ferroelectric and leakage-current properties at retention time of 10<sup>6</sup> s under different symmetry bending conditions. These results indicate that the BFMO film will be very practical in opto-electronic and storage device applications.