catena-Poly[[silver(I)-μ-2-[(pyrazin-2-yl-κ2N1:N4)aminomethyl]phenol] nitrate]

oleh: Zhao-Peng Deng, Shan Gao, Seik Weng Ng

Format: Article
Diterbitkan: International Union of Crystallography 2012-09-01

Deskripsi

The AgI atom in the polycationic salt, {[Ag(C11H11N3O)]NO3}n, shows a linear coordination [N—Ag—N = 175.0 (2)°]; the polymeric nature arises from bridging by the pyrazine portion of the ligand, resulting in chains extending parallel to [100]. The NO3− counter-ions surround the polymeric chain and interact only weakly with it [Ag...O = 2.701 (4) and 2.810 (5) Å]. Adjacent chains are linked into a three-dimensional network by O—H...O and N—H...O hydrogen bonds.