N-[Bis(dimethylamino)methylidene]-2-[(triphenylmethyl)sulfanyl]ethanaminium hexafluorophosphate
oleh: Adam Neuba, Ulrich Flörke, Gerald Henkel
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2011-05-01 |
Deskripsi
The molecular structure of the title compound, C26H32N3S+·PF6−, shows a protonated guanidyl group bridged by an ethylene linker with a tritylsulfanyl unit. The guanidinium (gua) unit displays charge delocalization over the three N—Cgua bonds. The N—C—C—S group shows a folded nonplanar conformation with a torsion angle of 158.4 (1)°. In the crystal, the cation and anion are linked by an N—H...F interaction.