Plasmon-Enhanced Blue-Light Emission of Stable Perovskite Quantum Dot Membranes

oleh: Kai Gu, Hongshang Peng, Siwei Hua, Yusong Qu, Di Yang

Format: Article
Diterbitkan: MDPI AG 2019-05-01

Deskripsi

A series of stable and color-tunable MAPbBr<sub>3&#8722;x</sub>Cl<sub>x</sub> quantum dot membranes were fabricated via a cost-efficient high-throughput technology. MAPbBr<sub>3&#8722;x</sub>Cl<sub>x</sub> quantum dots grown in-situ in polyvinylidene fluoride electrospun nanofibers exhibit extraordinary stability. As polyvinylidene fluoride can prevent the molecular group MA<sup>+</sup> from aggregating, MAPbBr<sub>3&#8722;x</sub>Cl<sub>x</sub> quantum dots are several nanometers and monodisperse in polyvinylidene fluoride fiber. As-prepared MAPbBr<sub>3&#8722;x</sub>Cl<sub>x</sub> quantum dot membranes exhibit the variable luminous color by controlling the Cl<sup>&#8722;</sup> content of MAPbBr<sub>3&#8722;x</sub>Cl<sub>x</sub> quantum dots. To improve blue-light emission efficiency, we successfully introduced Ag nanoparticle nanofibers into MAPbBr<sub>1.2</sub>Cl<sub>1.8</sub> quantum dot membranes via layer-by-layer electrospinning and obtained ~4.8 folds fluorescence enhancement for one unit. Furthermore, the originality explanation for the fluorescence enhancement of MAPbBr<sub>3&#8722;x</sub>Cl<sub>x</sub> quantum dots is proposed based on simulating optical field distribution of the research system.