[(R)-2,2-Bis(diphenylphosphanyl)-1,1&#8242;-binaphthyl-&#954;2P,P&#8242;]{2-[(2R)-1,2-diamino-1-(4-methoxyphenyl)-3-methylbutyl]-5-methoxyphenyl-&#954;C1}hydridoruthenium(II) benzene monosolvate

oleh: Kamaluddin Abdur-Rashid, Alan J. Lough

Format:	Article
Diterbitkan:	International Union of Crystallography 2012-12-01

Deskripsi

In the title complex, [Ru(C19H25N2O2)H(C44H32P2)]&#183;C6H6, the RuII ion is in a distorted octahedral coordination environment with the hydride H atom trans to the tertiary carbinamine N atom, giving an H&#8212;Ru&#8212;N angle of 160.8&#8197;(12)&#176;. The equatorial sites are occupied by two P atoms, the secondary carbinamine N atom and a coordinated C atom.

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[(R)-2,2-Bis(diphenylphosphanyl)-1,1&amp;#8242;-binaphthyl-&amp;#954;2P,P&amp;#8242;]{2-[(2R)-1,2-diamino-1-(4-methoxyphenyl)-3-methylbutyl]-5-methoxyphenyl-&amp;#954;C1}hydridoruthenium(II) benzene monosolvate

Deskripsi

[(R)-2,2-Bis(diphenylphosphanyl)-1,1′-binaphthyl-κ2P,P′]{2-[(2R)-1,2-diamino-1-(4-methoxyphenyl)-3-methylbutyl]-5-methoxyphenyl-κC1}hydridoruthenium(II) benzene monosolvate