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Hybrid Materials Based on <span style="font-variant: small-caps">l,d</span>-Poly(lactic acid) and Single-Walled Carbon Nanotubes as Flexible Substrate for Organic Devices
oleh: Patryk Fryń, Krzysztof Artur Bogdanowicz, Natalia Górska, Jakub Rysz, Piotr Krysiak, Mateusz Marzec, Monika Marzec, Agnieszka Iwan, Adam Januszko
Format: | Article |
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Diterbitkan: | MDPI AG 2018-11-01 |
Deskripsi
We report on the application of <span style="font-variant: small-caps;">l,d</span>-poly(lactic acid) (<span style="font-variant: small-caps;">l,d</span>-PLA) with dispersed Single-Walled Carbon Nanotubes (SWCN) as a flexible translucent electrode for organic devices. We used commercially available nanotubes in various weight ratios from 0 to 8% dispersed in chloroform polymeric solution by ultrasonication and were drop cast. The created hybrid materials were investigated by differential scanning calorimetry to determine the influence of SWCN content on the thermal behavior, while polarizing optical microscope was used to find the effect of mechanical deformations on the textures. Drop-cast films were studied by optical transmittance, conductivity, dielectric properties and by thermal imaging under applied potential. Thermal imaging provided evidence of visible voltage-activated conduction. Simple mechanical deformation such as bending with stretching at edge to ca. 90 and elongation test were performed. Moreover, interactions between <span style="font-variant: small-caps;">l,d</span>-poly(lactic acid) and SWCN were investigated by FT-IR and NMR spectroscopy. Finally, we can conclude that the thermographic examination of created films permits fast, simple and inexpensive localization of defects on the surface of <span style="font-variant: small-caps;">l,d</span>-PLA:SWCN film, together with the electrical properties of the films.