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Abstract We study the thermodynamic limit of the anisotropic XYZ spin chain with non-diagonal integrable open boundary conditions. Although the U(1)-symmetry is broken, by using the new parametrization scheme, we exactly obtain the surface energy and the excitation energy of the system, which has solved the difficulty in the inhomogeneous T − Q relation. With the boundary parameters in the regions making the Hamiltonian Hermitian, we have obtained the distribution patterns of the zeros of the eigenvalue of the transfer matrix for the ground state and the excited ones. We find that the surface and excitation energies depend on the parities of sites number N, due to the long-range Neel order in the bulk. The easy-axis and thermodynamic limit for all the regions of boundary parameters are studied. We also obtain the physical quantities in the thermodynamic limit of boundary XXZ model by taking the trigonometric limit.