Ionic liquid accelerates the crystallization of Zr-based metal–organic frameworks

oleh: Xinxin Sang, Jianling Zhang, Junfeng Xiang, Jie Cui, Lirong Zheng, Jing Zhang, Zhonghua Wu, Zhihong Li, Guang Mo, Yuan Xu, Jinliang Song, Chengcheng Liu, Xiuniang Tan, Tian Luo, Bingxing Zhang, Buxing Han

Format: Article
Diterbitkan: Nature Portfolio 2017-08-01

Deskripsi

Crystallization kinetics of metal-organic frameworks in conventional organic solvents are usually very slow. Here, the authors show that an ionic liquid medium accelerates considerably the formation of Zr-based metal-organic frameworks that are active catalysts in the Meerwein-Ponndorf-Verley reaction.