Sequence-regulated copolymerization based on periodic covalent positioning of monomers along one-dimensional nanochannels
oleh: Shuto Mochizuki, Naoki Ogiwara, Masayoshi Takayanagi, Masataka Nagaoka, Susumu Kitagawa, Takashi Uemura
| Format: | Article |
|---|---|
| Diterbitkan: | Nature Portfolio 2018-01-01 |
Deskripsi
Achieving sequence control in polymers is limited by the relative monomer reactivity and thus often statistically random copolymers are obtained. Here the authors show sequence control in radical polymerizations by immobilising the monomer on a porous coordination polymer and subsequent polymerization with a second free monomer.