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Poly[aquabis[μ2-2-(pyridin-4-ylsulfanyl)acetato]zinc]
oleh: Zhi-Chao Wang, Bo Ding, Xiu-Guang Wang, Xiao-Jun Zhao
Format: | Article |
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Diterbitkan: | International Union of Crystallography 2011-07-01 |
Deskripsi
The crystal structure of the title complex, [Zn(C7H6NO2S)2(H2O)]n, consists of extended layers parallel to (001) with 2-(pyridin-4-ylsulfanyl)acetate ligands bridging the ZnII atoms. The ZnII atom shows a distorted pentagonal–bipyramidal coordination environment. The ZnII and one O atom are situated on a crystallographic twofold rotation axis. In the crystal, intralayer O—H...O hydrogen-bond interactions help to consolidate the coordination layer.