Decandrinin, an unprecedented C9-spiro-fused 7,8-seco-ent-abietane from the Godavari mangrove Ceriops decandra
oleh: Hui Wang, Min-Yi Li, Félix Zongwe Katele, Tirumani Satyanandamurty, Jun Wu, Gerhard Bringmann
| Format: | Article |
|---|---|
| Diterbitkan: | Beilstein-Institut 2014-01-01 |
Deskripsi
Decandrinin (1), an unprecedented C9-spiro-fused 7,8-seco-ent-abietane, was obtained from the bark of an Indian mangrove, Ceriops decandra, collected in the estuary of Godavari, Andhra Pradesh. The constitution and the relative configuration of 1 were determined by HRMS (ESI) and extensive NMR investigations, and the absolute configuration by circular dichroism (CD) and optical-rotatory dispersion (ORD) spectroscopy in combination with quantum-chemical calculations. Decandrinin is the first 7,8-seco-ent-abietane.