catena-Poly[[[aquatris(pyridine-κN)nickel(II)]-μ-2,3,5,6-tetrachlorobenzene-1,4-dicarboxylato-κ2O1:O4] pyridine monosolvate]
oleh: Song Li, Chang-Ge Zheng, Peng Zhang, Pei-Pei Zhang
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2010-12-01 |
Deskripsi
The asymmetric unit of the title compound, {[Ni(C8Cl4O4)(C5H5N)3(H2O)]·C5H5N}n, contains two independent nickel(II) cations displaying a distorted octahedral coordination geometry provided by the N atoms of three pyridine molecules, the O atom of a water molecule, and O atoms of two monodentate μ2-bridging tetrachloroterephthalate dianions. The metal atoms are linked by the dianions into zigzag chains running parallel to [11overline{1}]. The crystal packing is stabilized by O—H...N and O—H...O hydrogen bonds.