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<p>Mesoscale convective systems (MCSs) are especially visible in the summertime when there is an advection of warm maritime air from the west. Advection of air masses is enriched by water vapour, the source of which can be found over the Mediterranean Sea. In propitious atmospheric conditions, and thus significant convection, atmospheric instability or strong vertical thermal gradient leads to the development of strong thunderstorm systems. In this paper, we discuss one case of MCSs, which generated a significant amount of <span class="inline-formula">+</span>CG (cloud-to-ground), <span class="inline-formula">−</span>CG and intracloud (IC) discharges. We have focused on the ELF (extremely low frequency; <span class="inline-formula"><i>&lt;</i></span> 1 kHz) electromagnetic field measurements, since they allow us to compute the charge moments of atmospheric discharges. Identification of the MCSs is a complex process, due to many variables which have to be taken into account. For our research, we took into consideration a few tools, such as cloud reflectivity, atmospheric soundings and data provided by PERUN (Polish system of the discharge localisation system), which operates in a very high frequency (VHF) range (113.5–114.5 MHz). Combining the above-described measurement systems and tools, we identified a MCS which occurred in Poland on 23 July 2009. Furthermore, it fulfilled our requirements since the thunderstorm crossed the path of the DEMETER (Detection of Electro-Magnetic Emissions Transmitted from Earthquake Regions) overpass.</p>