Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ2O,O′}tris(thiocyanato-κN)praseodymium(III) monohydrate
oleh: Jian-Feng Liu, Jia-Lu Liu, Guo-Liang Zhao
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2009-11-01 |
Deskripsi
The asymmetric unit of title compound, [Pr(NCS)3(C15H15NO2)3]·H2O, consists of three Schiff base 2-methoxy-6-[(4-methylphenyl)iminomethyl]phenol (HL) ligands, three independent thiocyanate anions and an uncoordinated water molecule. The PrIII ion is nine-coordinated. The thiocyanate anions coordinate to the PrIII ion via the N atoms and the three HL ligands chelate the PrIII ion via the phenoxy and methoxy O atoms. The protonated imine N atoms are involved in intramolecular hydrogen bonds with the phenolate groups.