Dibromido(4,4′-dimethyl-2,2′-bipyridine-κ2N,N′)(dimethyl sulfoxide-κO)cadmium
oleh: Sadif A. Shirvan, Sara Haydari Dezfuli
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2012-07-01 |
Deskripsi
In the title compound, [CdBr2(C12H12N2)(C2H6OS)], the CdII atom is five-coordinated in a distorted trigonal–bipyramidal geometry by two N atoms from one 4,4′-dimethyl-2,2′-bipyridine (DMBP) ligand, one O atom from a dimethyl sulfoxide (DMSO) ligand and two Br atoms. A weak intramolecular C—H...O hydrogen bond occurs between the DMBP and DMSO ligands. π–π stacking between pyridine rings [centroid–centroid distances = 3.682 (3) and 3.598 (3) Å] is observed in the crystal.