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The asymmetric unit of the title compound, C14H14O6, a monomeric compound of poly(butylene 2,5-furandicarboxylate), consists of one half-molecule, the whole all-trans molecule being generated by an inversion centre. In the crystal, the molecules are interconnected via C—H...O interactions, forming a molecular sheet parallel to (10\overline{2}). The molecular sheets are further linked by C—H...π interactions.