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In order to further promote the research and application of MgO expansion agent in concrete field, this paper carried out the effect of different humidity and temperature conditions on the expansion properties of mortar and mortar specimens mixed with MgO expansion agent. In addition, the mechanism of the factors affecting the sensitivity of the MgO expansion agent is revealed by combining microscopic technology. The results show that the higher the curing temperature and the greater the curing humidity, the greater the expansion efficiency of the MgO expansion agent. The temperature of 20~40°C has no obvious effect on the efficiency of the MgO expansion agent, but the expansion value of the specimen doubles as the temperature rises to 40~80°C. Besides, the higher the curing humidity, the better the expansion efficiency of the MgO expansion agent, but the MgO expansion agent is more sensitive to the low humidity environment, and the specimen shrinks in the lower humidity environment (RH=60%).