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The purpose of this research is to impose a semi-analytical method called the iterative method to the chemical kinetics system, which appears in the form of a system of ordinary differential equations. To test the accuracy of the standard iterative method, we have applied the classical fourth-order Runge–Kutta method and the iterative method to the chemical kinetics system. It is significantly notable that approximate analytical precisions of standard iterative method made a high agreement with those obtained from the fourth-order Runge–Kutta technique. Numerical outputs and solution procedures indicate that iterative method can be easily applicable to a large class of scientific numeric applications with high accuracy.