Diaqua[5,5′-dicarboxy-2,2′-(propane-1,3-diyl)bis(1H-imidazole-4-carboxylato)]manganese(II)
oleh: Huai-Xia Yang, Xiaoli Zhou, Guanghua Jin, Xiang-Ru Meng
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2011-05-01 |
Deskripsi
The complex molecule of the title compound, [Mn(C13H10N4O8)(H2O)2] or [Mn(H4pbidc)(H2O)2] (H6pbidc = 2,2′-(propane-1,3-diyl)bis(1H-imidazole-4,5-dicarboxylic acid), has 2 symmetry with the twofold rotation axis running through the Mn2+ cation and the central C atom of the propanediyl unit. The cation is six-coordinated by two N atoms and two O atoms from one H4pbidc2− anion and two water O atoms in a considerably distorted octahedral coordination. In the crystal, adjacent molecules are linked through O—H...O and N—H...O hydrogen bonds into a three-dimensional network.