A redetermination of bis(5,5′-diethylbarbiturato)bis(imidazole)cobalt(II)
oleh: Wen-Dong Song, Peng-Zhi Hong, Run-Zhen Fan
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2008-02-01 |
Deskripsi
The title complex, [Co(C8H12N2O3)2(C3H4N2)2], whose structure was first determined by Wang & Craven [(1971). J. Chem. Soc. D, pp. 290–291], has been redetermined with improved precision. A crystallographic twofold rotation axis passes through the Co atom, which is tetrahedrally coordinated by two N atoms from two barbital ligands and two N atoms from two imidazole ligands. The molecules are self-assembled via intermolecular N—H...O hydrogen-bonding interactions into a supramolecular network.