Enhanced Thermoelectric Properties of WS<sub>2</sub>/Single-Walled Carbon Nanohorn Nanocomposites

oleh: Ji Hoon Kim, Seunggun Yu, Sang Won Lee, Seung-Yong Lee, Keun Soo Kim, Yoong Ahm Kim, Cheol-Min Yang

Format: Article
Diterbitkan: MDPI AG 2020-02-01

Deskripsi

Recently, two-dimensional tungsten disulfide (WS<sub>2</sub>) has attracted attention as a next generation thermoelectric material due to a favorable Seebeck coefficient. However, its thermoelectric efficiency still needs to be improved due to the intrinsically low electrical conductivity of WS<sub>2</sub>. In the present study, thermoelectric properties of WS<sub>2</sub> hybridized with highly conductive single-walled carbon nanohorns (SWCNHs) were investigated. The WS<sub>2</sub>/SWCNH nanocomposites were fabricated by annealing the mixture of WS<sub>2</sub> and SWCNHs using a high-frequency induction heated sintering (HFIHS) system. By adding SWCNHs to WS<sub>2</sub>, the nanocomposites exhibited increased electrical conductivity and a slightly decreased Seebeck coefficient with the content of SWCNHs. Hence, the maximum power factor of 128.41 &#956;W/mK<sup>2</sup> was achieved for WS<sub>2</sub>/SWCNHs with 0.1 wt.% SWCNHs at 780 K, resulting in a significantly improved thermoelectric figure of merit (<i>zT</i>) value of 0.027 compared to that of pristine WS<sub>2</sub> with <i>zT</i> 0.017.