Bis(pentafluorobenzenethiolato-κS){(pentafluorophenyl)phenyl[3,4,5,6-tetrafluoro-2-(pentafluorophenylsulfanyl)phenyl]phosphane-κ2P,S}platinum(II) dichloromethane hemisolvate
oleh: Sylvain Bernès, Hugo Torrens
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2016-05-01 |
Deskripsi
In the title compound, [Pt(C6F5S)2(C24H5F14PS)]·0.5CH2Cl2, the complex features a square-planar PtII atom coordinated by two thiolate ligands and one chelating bidentate P/S ligand, forming a five-membered metallacycle. The monodentate SC6F5 ligands give a weak parallel displaced π–π interaction. In the chelating ligand, the geometry for both S and P donor atoms is consistent with sp3 hybridization. The complex conformation is identical to that previously described for the compound bearing 2,3,5,6-tetrafluorophenylthiolate in place of pentafluorophenylthiolate groups. The lattice solvent, CH2Cl2, is disordered over inversion centers in P-1, affording a hemisolvate.