Tetrakis(1-allyl-1H-imidazole-κN3)bis(thiocyanato-κN)manganese(II)
oleh: Juan Zhao, Yan-Ling Jin
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2012-01-01 |
Deskripsi
The structure of the title compound, [Mn(NCS)2(C6H8N2)4], consists of isolated molecules of [Mn(NCS)2(Aim)4] (Aim = 1-allylimidazole), which contain a compressed octahedral MnN6 chromophore (site symmetry overline1). The NCS− anions are trans and four N atoms from the Aim ligands define the equatorial plane. The mean Mn—N(Aim) and Mn—N(NCS) distances are 2.270 and 2.229 Å, respectively. Weak C—H...N interactions contribute to the crystal packing stability.