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Herein we present a facile synthesis of the graphene oxide-decorated binary transition metal oxides of Bi₂O₃ and MnO₂ nanocomposites (Bi₂O₃/MnO₂/GO) and their applications in the voltammetric detection of lead ions (Pb²⁺) in water samples. The surface morphologies, crystal structures, electroactive surface area, and charge transferred resistance of the Bi₂O₃/MnO₂/GO nanocomposites were investigated through the scanning electron microscopy (SEM), power X-ray diffraction (XRD), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS) techniques, respectively. The Bi₂O₃/MnO₂/GO nanocomposites were further decorated onto the surface of a glassy carbon electrode (GCE), and Pb²⁺ was quantitatively analyzed by using square-wave anodic stripping voltammetry (SWASV). We explored the effect of the analytical parameters, including deposition potential, deposition time, and solution pH, on the stripping peak current of Pb²⁺. The Bi₂O₃/MnO₂/GO nanocomposites enlarged the electroactive surface area and reduced the charge transferred resistance by significant amounts. Moreover, the synergistic enhancement effect of MnO₂, Bi₂O₃ and GO endowed Bi₂O₃/MnO₂/GO/GCE with extraordinary electrocatalytic activity toward Pb²⁺ stripping. Under optimal conditions, the Bi₂O₃/MnO₂/GO/GCE showed a broad linear detection range (0.01–10 μM) toward Pb²⁺ detection, with a low limit of detection (LOD, 2.0 nM). The proposed Bi₂O₃/MnO₂/GO/GCE electrode achieved an accurate detection of Pb²⁺ in water with good recoveries (95.5–105%).