Find in Library
Search millions of books, articles, and more
Indexed Open Access Databases
Characterization of atmospheric methane release in the outer Mackenzie River delta from biogenic and thermogenic sources
oleh: D. Wesley, D. Wesley, S. Dallimore, R. MacLeod, T. Sachs, D. Risk
| Format: | Article |
|---|---|
| Diterbitkan: | Copernicus Publications 2023-12-01 |
Deskripsi
<p>The Mackenzie River delta is the second largest Arctic river delta in the world. Thin and destabilizing permafrost coupled with vast natural gas reserves at depth, high organic-content soils, and a high proportion of wetlands create a unique ecosystem conducive to high rates of methane (CH<span class="inline-formula"><sub>4</sub></span>) emission from biogenic and thermogenic sources. Hotspots are known to have a significant contribution to summertime CH<span class="inline-formula"><sub>4</sub></span> emissions in the region. Still, little research has been done to determine how often geologic or biogenic CH<span class="inline-formula"><sub>4</sub></span> contributes to hotspots in the Mackenzie River delta. In the present study, stable carbon isotope analysis was used to identify the source of CH<span class="inline-formula"><sub>4</sub></span> at several aquatic and terrestrial sites thought to be hotspots of CH<span class="inline-formula"><sub>4</sub></span> flux to the atmosphere. Walking transects and point samples of atmospheric CH<span class="inline-formula"><sub>4</sub></span> and CO<span class="inline-formula"><sub>2</sub></span> concentrations were measured. Source stable carbon isotope (<span class="inline-formula"><i>δ</i><sup>13</sup></span>C-CH<span class="inline-formula"><sub>4</sub></span>) signatures were derived from keeling plots of point samples and ranged from <span class="inline-formula">−42 ‰</span> to <span class="inline-formula">−88 ‰</span> <span class="inline-formula"><i>δ</i><sup>13</sup></span>C-CH<span class="inline-formula"><sub>4</sub></span>, identifying both biogenic and thermogenic sources. A CH<span class="inline-formula"><sub>4</sub></span> source was determined for eight hotspots, two of which were thermogenic in origin (<span class="inline-formula">−42.5 ‰</span>, <span class="inline-formula">−44.7 ‰</span>), four of which were biogenic in origin (<span class="inline-formula">−71.9 ‰</span> to <span class="inline-formula">−88.3 ‰</span>), and two of which may have been produced by the oxidation of biogenic CH<span class="inline-formula"><sub>4</sub></span> (<span class="inline-formula">−53.0 ‰</span>, <span class="inline-formula">−63.6 ‰</span>), as evidenced by <span class="inline-formula"><i>δ</i><sup>13</sup></span>C-CH<span class="inline-formula"><sub>4</sub></span> signatures. This indicates that the largest hotspots of CH<span class="inline-formula"><sub>4</sub></span> production in the Mackenzie River delta are caused by a variety of sources.</p>