catena-Poly[4-methylmorpholin-4-ium [[dichloridobismuth(III)]-di-μ-chlorido]]
oleh: Ying-Chun Wang
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2012-02-01 |
Deskripsi
The asymmetric unit of the title complex, {(C5H12NO)[BiCl4]}n, contains two bridging and two cis non-bridging chloride ligands coordinated to a central BiIII atom, and one 4-methylmorpholin-4-ium cation. The BiIII atoms are linked by the bridging chloride ligands into linear chains parallel to the c axis. The chloride ions create a pseudo-octahedral geometry about each BiIII atom. Bifurcated N—H...Cl hydrogen bonds link the cations to the anionic chains.