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The energy level scheme of 188Os has been established on the basis of y-y coincidence measurements. Ge (Li) and HPGe detectors were employed to study the gamma spectra produced in the -decay of 188Re to 188Os. Fourteen new transitions and four new levels at 1660, 1871, 1948 188and 2034 keV are suggested. Relative intensities from singles measurements, branching ratios  and loft values were calculated and multipolarities, spins and parities deduced