catena-Poly[[dichloridozinc(II)]-μ-1,4-bis(1H-imidazol-1-yl)benzene]
oleh: Yang Niu, Ling Yuan, Shan-Ji Nan, Cheng-Bi Xu, Yi Nan
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2010-12-01 |
Deskripsi
In the title one-dimensional coordination polymer, [ZnCl2(C12H10N4)]n, the ZnII atom (site symmetry 2) is coordinated by two chloride ions and two 1,4-bis(imidazol-1-yl)benzene ligands, generating a distorted tetrahedral ZnCl2N2 geometry for the metal ion. The bridging ligand, which is completed by crystallographic inversion symmetry, links the ZnII atoms into zigzag chains propagating in [101]. Within the ligand, the dihedral angle between the central benzene ring and terminal imidazole ring is 27.82 (13)°.