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A three-armed cryptand with triazine and pyridine units: synthesis, structure and complexation with polycyclic aromatic compounds
oleh: Claudia Lar, Adrian Woiczechowski-Pop, Attila Bende, Ioana Georgeta Grosu, Natalia Miklášová, Elena Bogdan, Niculina Daniela Hădade, Anamaria Terec, Ion Grosu
Format: | Article |
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Diterbitkan: | Beilstein-Institut 2018-06-01 |
Deskripsi
The aromatic nucleophilic substitution reaction based synthesis of a three-armed cryptand displaying 2,4,6-triphenyl-1,3,5-triazine units as caps and pyridine rings in the bridges, along with NMR, MS and molecular modelling-based structural analysis of this compound are reported. Appropriate NMR and molecular modelling investigations proved the formation of 1:1 host–guest assemblies between the investigated cryptand and some polynuclear aromatic hydrocarbons or their derivatives.