(R)-[1-(2-Chlorophenyl)-2-methoxy-2-oxoethyl][2-(thiophen-2-yl)ethyl]ammonium (+)-camphor-10-sulfonate acetone monosolvate
oleh: Deng-Ke Liu, Ying Liu, Shuai Mu, Yan-Shu Liang
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2010-12-01 |
Deskripsi
The title compound, C15H17ClNO2S+·C10H15O4S−·C3H6O, was synthesized by N-alkylation of α-amino-(2-chlorophenyl)acetate with 2-thienylethyl p-toluenesulfonate, followed by reaction with (+)-camphor-10-sulfonic acid. In the crystal, the cations and anions are linked through N—H...O hydrogen bonds. The thiophene ring of the cation was found to be disordered over two sites, with refined occupancies of 0.798 (4) and 0.202 (4).