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Deciphering anthropogenic and biogenic contributions to selected non-methane volatile organic compound emissions in an urban area
oleh: A. Peron, M. Graus, M. Graus, M. Striednig, C. Lamprecht, G. Wohlfahrt, T. Karl
| Format: | Article |
|---|---|
| Diterbitkan: | Copernicus Publications 2024-06-01 |
Deskripsi
<p>The anthropogenic and biogenic contributions of isoprene, monoterpenes, sesquiterpenes and methanol in an urban area were estimated based on direct eddy covariance flux observations during four campaigns between 2018 and 2021. While these compounds are typically thought to be dominated by biogenic sources on regional and global scales, the role of potentially significant anthropogenic emissions in urban areas has been recently debated. Typical fluxes of isoprene, monoterpenes and sesquiterpenes were on the order of 0.07 <span class="inline-formula">±</span> 0.02, 0.09 and 0.003 nmol m<span class="inline-formula"><sup>−2</sup></span> s<span class="inline-formula"><sup>−1</sup></span> during spring. During summer, emission fluxes of isoprene, monoterpenes and sesquiterpenes were higher on the order of 0.85 <span class="inline-formula">±</span> 0.09, 0.11 and 0.004 nmol m<span class="inline-formula"><sup>−2</sup></span> s<span class="inline-formula"><sup>−1</sup></span>. It was found that the contribution of the anthropogenic part is strongly seasonally dependent. For isoprene, the anthropogenic fraction can be as high as 64 % in spring but is typically very low <span class="inline-formula"><</span> 18 % during the summer season. For monoterpenes, the anthropogenic fraction was estimated to be between 43 % in spring and less than 20 % in summer.</p> <p>With values of 2.8 nmol m<span class="inline-formula"><sup>−2</sup></span> s<span class="inline-formula"><sup>−1</sup></span> in spring and 3.2 nmol m<span class="inline-formula"><sup>−2</sup></span> s<span class="inline-formula"><sup>−1</sup></span> in summer, methanol did not exhibit a significant seasonal variation of observed surface fluxes. However, there was a difference in emissions between weekdays and weekends (about 2.3 times higher on weekdays in spring). This suggests that methanol emissions are likely influenced by anthropogenic activities during all seasons.</p>