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Mine floods caused by water-bearing collapse columns are one of the most significant types of coal mine disasters in advanced detection. The transient electromagnetic method (TEM), one of the most effective means, can detect the collapse column in coal mines. However, the research on TEM used on the ground is mainly limited to half-space that does not follow underground mining conditions. This research used the whole-space TEM to detect the water-bearing collapse columns in front of the roadway. Based on the time-domain finite element method (TDFEM) and actual coal-measure strata data, this paper built the whole-space geo-electric models, summarized response characteristics, and proposed “geometric gravity center” effect. The results showed that the simulation based on TDFEM could accurately reflect the TEM response law, and the advanced detection using TEM in a mine environment was consistent with the actual situation.