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Study of Atomic Layer Deposition Nano-Oxide Films on Corrosion Protection of Al-SiC Composites
oleh: Hou-Jen Chen, Ying-Chu Chen, Pi-Chen Lin, Kaifan Lin, Jonathan C. Lin, Miin-Jang Chen, Hsin-Chih Lin
Format: | Article |
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Diterbitkan: | MDPI AG 2023-09-01 |
Deskripsi
In recent years, aluminum matrix composites (AMCs) have attracted attention due to their promising properties. However, the presence of ceramic particles in the aluminum matrix renders AMCs a high corrosion rate and makes it challenging to use traditional corrosion protection methods. In this study, atomic layer deposition (ALD) techniques were used to deposit HfO<sub>2</sub>, ZrO<sub>2</sub>, TiO<sub>2</sub>, and Al<sub>2</sub>O<sub>3</sub> thin films on AMC reinforced with 20 vol.% SiC particles. Our results indicate that the presence of micro-cracks between the Al matrix and SiC particles leads to severe micro-crack-induced corrosion in Al-SiC composites. The ALD-deposited films effectively enhance the corrosion resistance of these composites by mitigating this micro-crack-induced corrosion. Among these four atomic-layer deposited films, the HfO<sub>2</sub> film exhibits the most effective reduction in the corrosion current density of Al-SiC composites in a 1.5 wt% NaCl solution from 1.27 × 10<sup>−6</sup> A/cm<sup>2</sup> to 5.89 × 10<sup>−11</sup> A/cm<sup>2</sup>. The electrochemical impedance spectroscopy (EIS) investigation shows that HfO<sub>2</sub> deposited on Al-SiC composites has the largest R<sub>p</sub> value of 2.0 × 10<sup>16</sup>. The HfO<sub>2</sub> film on Al-SiC composites also exhibits effective inhibition of pitting corrosion, remaining at grade 10 even after 96 h of a salt spray test.