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Mixed ligand complexes of alkaline earth metals: Part XII. Mg(II), Ca(II), Sr(II) and Ba(II) complexes with 5-chlorosalicylaldehyde and salicylaldehyde or hydroxyaromatic ketones
oleh: Prasad R.N., Agrawal M., Sharma M.
Format: | Article |
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Diterbitkan: | Serbian Chemical Society 2002-01-01 |
Deskripsi
The reactions of alkaline earth metal chlorides with 5-chlorosalicylaldehyde and salicylaldehyde, 2-hydroxyacetophenone or 2-hydroxypropiophenone have been carried out in 1: 1: 1 mole ratio and the mixed ligand complexes of the type MLL’(H2O)2 (where M = Mg(II), Ca(II), Sr(II) and Ba(II),HL= 5-chlorosalicylaldehyde and HL’= salicylaldehyde, 2-hydroxyacetophenone or 2-hydroxypropiophenone) have been isolated. These complexes were characterized by TLC, conductance measurements, IR and 1H-NMR spectra.