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Let  be the Lie algebra of  the semi-direct sum of the real vector space   and the Lie algebra  of the sets of all  real matrices. In this paper, a Frobenius functional is constructed in order for the Lie algebra  to be the real Frobenius Lie algebra of dimension 8. Moreover,  a bilinear form corresponding to this Frobenius functional is symplectic. Then the obtained symplectic bilinear form induces the left-symmetric algebra structures on . In other words, the Lie algebra   is the left-symmetric algebra. In particular, we give the formulas of its left-symmetric algebra structure explicitely. The left-symmetric algebra structures for case of higher dimension of this Lie algebra type are still an open problem to be investigated.