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We report a rapid synthesis method for producing CsSnCl₃:Mn²⁺ perovskites, derived from SnF₂, and investigate the effects of rapid thermal treatment on their photoluminescence properties. Our study shows that the initial CsSnCl₃:Mn²⁺ samples exhibit a double luminescence peak structure with PL peaks at approximately 450 nm and 640 nm, respectively. These peaks originate from defect-related luminescent centers and the 4T¹→6A¹ transition of Mn²⁺. However, as a result of rapid thermal treatment, the blue emission is significantly reduced and the red emission intensity is increased nearly twofold compared to the pristine sample. Furthermore, the Mn²⁺-doped samples demonstrate excellent thermal stability after the rapid thermal treatment. We suggest that this improvement in photoluminescence results from enhanced excited-state density, energy transfer between defects and the Mn²⁺ state, as well as the reduction of nonradiative recombination centers. Our findings provide valuable insights into the luminescence dynamics of Mn²⁺-doped CsSnCl₃ and open up new possibilities for controlling and optimizing the emission of rare-earth-doped CsSnCl₃.