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Ammonia (NH₃) volatilization from paddy fields is a major issue which leads to poor fertilizer use efficiency and is considered a severe threat to the atmosphere. The previous research studies gave importance to the use of nitrogen fertilizers to mitigate NH₃ volatilization, while very little emphasis was given to the role of other fertilizers, such as phosphorus (P), for the alleviation of NH₃ volatilization in rice fields. Considering P importance herein, we conducted two consecutive field experiments using an innovative, controlled-release, phosphorus-blended fertilizer (CRPBF, with levels CRP0, CRP1, and CRP2). We compared CP0 (in which no fertilizer was applied), CP1 (112.5 kg P ha⁻¹ P of locally recommended fertilizers), and CP2: (P and K blended fertilizers) to determine the best possible way to reduce NH₃ volatilization without affecting the yield and quality of rice. The results of the study suggested that the yield of rice increased significantly with the application of CRP1 (11.11 t ha⁻¹) and CRP2 (11.99 t ha⁻¹). The addition of CRP1 and CRP2 to the rice field also enhanced yield-related components, i.e., panicle weight, total spikelets per unit area, spikelets per panicle, and above-ground biomass. CRP0 showed a lower yield and related components when compared to CP2. The addition of CRP1 and CRP2 demonstrated lower protein contents when compared to other treatments. The CRPBF application improved starch content and taste scores, and reduced the chalkiness of the rice grain during both years. The results showed a decreasing trend in NH₃ volatilization from CRPBF amendments by improving the nitrogen use efficiency traits when compared to other treatments: CRP2, CRP1, and CRP0 reduced NH₃ volatilization by 45%, 35%, and 15%, respectively. The results of this study indicate that, due to the episodic nature of NH₃ volatilization, CRPBFs with 50% P and 100% P can markedly reduce NH₃ volatilization from paddy fields without compromising the yield and quality of the crop, and could be a promising alternative to the ordinary commercial fertilizers used in rice fields.