catena-Poly[[{2-[(2-hydroxyethyl)iminomethyl]-6-methoxyphenolato}copper(II)]-μ-thiocyanato]
oleh: Ling-Wei Xue, Gan-Qing Zhao, Yong-Jun Han, Yun-Xiao Feng
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2010-09-01 |
Deskripsi
In the title thiocyanate-bridged polynuclear copper(II) complex, [Cu(C10H12NO3)(NCS)]n, the Cu atom is five-coordinated in a square-pyramidal geometry, with one phenolato O, one imino N and one hydroxy O atom of a Schiff base ligand and one thiocyanato N atom defining the basal plane, and with one thiocyanato S atom occupying the apical position. In the crystal structure, pairs of adjacent complex molecules are linked through intermolecular O—H...O hydrogen bonds into dimers. The dimers are further linked via Cu...S interactions, forming two-dimensional layers parallel to the bc plane.