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The hybrid step-up converter is a fifth-order system with a dc gain greater than the traditional second-order step-up configuration. Considering their high order, several state variables are accessible for feedback purposes in the control of such systems. Therefore, choosing the best state variables is essential since they influence the system’s dynamic response and stability. This work proposes a methodical method to identify the appropriate state variables in implementing a sliding-mode (SM) controlled hybrid boost converter. A thorough comparison of two SM controllers based on various feedback currents is conducted. The frequency response technique is used to demonstrate how the SM method employing the current through the output inductor leads to an unstable response. The right-half s-plane poles and zeroes in the converter’s inner-loop transfer function, which precisely cancel one another, are what is causing the instability. On the other hand, a stable system may result from employing a SM controller with the current through the input inductor. Lastly, some experimental outcomes using the preferred SM control method are provided.