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Detecting the spin-polarization of edge states in graphene nanoribbons
oleh: Jens Brede, Nestor Merino-Díez, Alejandro Berdonces-Layunta, Sofía Sanz, Amelia Domínguez-Celorrio, Jorge Lobo-Checa, Manuel Vilas-Varela, Diego Peña, Thomas Frederiksen, José I. Pascual, Dimas G. de Oteyza, David Serrate
Format: | Article |
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Diterbitkan: | Nature Portfolio 2023-10-01 |
Deskripsi
Abstract Low dimensional carbon-based materials can show intrinsic magnetism associated to p-electrons in open-shell π-conjugated systems. Chemical design provides atomically precise control of the π-electron cloud, which makes them promising for nanoscale magnetic devices. However, direct verification of their spatially resolved spin-moment remains elusive. Here, we report the spin-polarization of chiral graphene nanoribbons (one-dimensional strips of graphene with alternating zig-zag and arm-chair boundaries), obtained by means of spin-polarized scanning tunnelling microscopy. We extract the energy-dependent spin-moment distribution of spatially extended edge states with π-orbital character, thus beyond localized magnetic moments at radical or defective carbon sites. Guided by mean-field Hubbard calculations, we demonstrate that electron correlations are responsible for the spin-splitting of the electronic structure. Our versatile platform utilizes a ferromagnetic substrate that stabilizes the organic magnetic moments against thermal and quantum fluctuations, while being fully compatible with on-surface synthesis of the rapidly growing class of nanographenes.