Curcuminoid–BF2 complexes: Synthesis, fluorescence and optimization of BF2 group cleavage
oleh: Henning Weiss, Jeannine Reichel, Helmar Görls, Kilian Rolf Anton Schneider, Mathias Micheel, Michael Pröhl, Michael Gottschaldt, Benjamin Dietzek, Wolfgang Weigand
| Format: | Article |
|---|---|
| Diterbitkan: | Beilstein-Institut 2017-10-01 |
Deskripsi
Eight difluoroboron complexes of curcumin derivatives carrying alkyne groups containing substituents have been synthesized following an optimised reaction pathway. The complexes were received in yields up to 98% and high purities. Their properties as fluorescent dyes have been investigated. Furthermore, a strategy for the hydrolysis of the BF2 group has been established using aqueous methanol and sodium hydroxide or triethylamine.