Find in Library
Search millions of books, articles, and more
Indexed Open Access Databases
Exfoliation of Al-Residual Multilayer MXene Using Tetramethylammonium Bases for Conductive Film Applications
oleh: Emi Saita, Masaki Iwata, Yuki Shibata, Yuki Matsunaga, Rie Suizu, Rie Suizu, Kunio Awaga, Jun Hirotani, Jun Hirotani, Haruka Omachi, Haruka Omachi
Format: | Article |
---|---|
Diterbitkan: | Frontiers Media S.A. 2022-03-01 |
Deskripsi
This study describes the concise exfoliation of multilayer Ti3C2Tx MXene containing residual aluminum atoms. Treatment with tetramethylammonium base in a co-solvent of tetrahydrofuran and H2O produced single-layer Ti3C2Tx, which was confirmed via atomic force microscopy observations, with an electrical conductivity 100+ times that of Ti3C2Tx prepared under previously reported conditions. The scanning electron microscopy and X-ray diffraction measurements showed that the exfoliated single-layer Ti3C2Tx MXenes were reconstructed to assembled large-domain layered films, enabling excellent macroscale electric conductivity. X-ray photoelectron spectroscopy confirmed the complete removal of residual Al atoms and the replacement of surface fluorine atoms with hydroxy groups. Using the exfoliated dispersion, a flexible transparent conductive film was formed and demonstrated in an electrical application.