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Protective coatings for bronze relics should adhere to the basic principles of cultural relic preservation, such as not altering the color and appearance of the artifacts, and being moderately combined with the artifacts to resist erosion due to external environments (such as water and gas). This paper presents the development of a physically crosslinked supramolecular hydrogel produced from guanidinium-based chitosan (GC). The hydrogel exhibits the excellent adsorption protection of bronze, and the addition of clay enhances the water barrier properties of the chitosan film. The supramolecular interaction between sodium polyacrylate/GC/clay confers corrosion buffering capability to the hydrogel coating in corrosive environments, and the gel coating can be self-healing at room temperature for 24 h. The fabricated nanocomposites were comprehensively characterized using various methods (Fourier transform infrared spectroscopy, X-ray diffraction, thermogravimetric analysis, X-ray photoelectron spectroscopy, scanning electron microscopy, etc.). The electrochemical properties of coated specimens were evaluated, and the impedance spectrum revealed a large impedance arc indicating high charge resistance, which has a corrosion resistance effect.