Sol-gel Synthesis and Photocatalytic Activity of La<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub>/HZSM-5

oleh: QU Jia-hui, DU Ling, ZHAO Fang-xin, YANG Li-li, ZHANG Wen-jie

Format: Article
Diterbitkan: Journal of Materials Engineering 2017-07-01

Deskripsi

La<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub>/HZSM-5 photocatalysts were prepared by sol-gel method, and its photocatalytic activity was studied. The results show that the original crystal phase of La<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub> is not changed after loading La<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub> on HZSM-5,and is still perovskite structure. La<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub> is dispersed on the surface of HZSM-5 after loading to apparent increasing specific surface area and formation of new mesoporous structure. The growth of La<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub> is constrainted by HZSM-5, resulting in the reduction of grain size. The absorption boundary has a blue shift and the band gap increases with decreasing La<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub> loading content. Binding energies of La3d and O1s electrons move to higher energy after loading La<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub> on HZSM-5. La<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub>/HZSM-5 has enhanced photocatalytic activity as compared to La<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub>. 91.8% of the reactive brilliant red(RBR) X-3B is decolorized on 70%La<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub>/HZSM-5 after 120min of UV irradiation, while only 31.7% of the dye is removed on La<sub>2</sub>Ti<sub>2</sub>O<sub>7</sub>.