trans-Carbonylchloridobis(tri-o-tolylphosphane-κP)rhodium(I)
oleh: Stefan Warsink, Renier Koen, Andreas Roodt
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2011-12-01 |
Deskripsi
In the title compound, [RhCl(C21H21P)2(CO)], the coordination geometry around the RhI atom is slightly distorted square-planar with the phosphane ligands in trans positions with respect to each other. The chloride and carbonyl ligands show positional disorder, and the RhI atom lies on a center of inversion. The effective cone angle ΘE for the title compound is 169.0 (3)°. There are no significant intermolecular interactions.