catena-Poly[[(1,10-phenanthroline)cadmium(II)]-μ-2-(1,3-benzimidazol-2-ylsulfanyl)acetato-κ3N1,O:N3]
oleh: Lin Cheng, Yan-Yan Sun, Ya-Wen Zhang, Jian-Quan Wang
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2009-01-01 |
Deskripsi
In title compound, [Cd(C9H6N2O2S)(C12H8N2)]n, the CdII atom is in a distorted tetragonal-pyramidal environment, coordinated by one chelating 1,10-phenanthroline ligand, one chelating 2-(1,3-benzimidazol-2-ylsulfanyl)acetate (bia) ligand bound through one N atom and one O atom of the carboxyl group, and one N atom from a second bia ligand. Each bia ligand acts as bridge between CdII ions, forming one-dimensional coordination polymers along [010], with a shortest Cd...Cd distance of 4.27 (2) Å.