Peroxymonosulfate Activation by CuO-Fe<sub>2</sub>O<sub>3</sub>-Modified Ni Foam: A <sup>1</sup>O<sub>2</sub> Dominated Process for Efficient and Stable Degradation of Tetracycline

oleh: Xueqing Ren, Peng Xu, Ke Tian, Menghan Cao, Fengyin Shi, Guangshan Zhang

Format: Article
Diterbitkan: MDPI AG 2023-02-01

Deskripsi

The post-separation of powder catalysts restricts the practical application of peroxymonosulfate (PMS)-based advanced oxidation technology. Hence, we fabricated CuO-Fe<sub>2</sub>O<sub>3</sub>-modified Ni foam (CFO-NF) using a facile hydrothermal method for an efficient PMS activation. The CFO-NF/PMS system could achieve a 97.9% tetracycline hydrochloride (TC) removal efficiency in 60 min with four pieces of CFO-NF and 0.4 mmol L<sup>−1</sup> of PMS. The removal efficiency was maintained at ˃85% even after five cycles, indicating the excellent stability of CFO-NF composites. The conversion among Fe(III)/Fe(II), Cu(II)/Cu(I), and Ni(III)/Ni(II) accelerated the PMS decomposition, verifying the synergy between CuO-Fe<sub>2</sub>O<sub>3</sub> and Ni foam. The trapping experiments and EPR detection confirmed that abundant active species (•OH, SO<sub>4</sub><sup>•−</sup>, O<sub>2</sub><sup>•−</sup>, and <sup>1</sup>O<sub>2</sub>) were produced in the CFO-NF/PMS system, accounting for the existence of radical pathways and a non-radical pathway, in which <sup>1</sup>O<sub>2</sub> (non-radical pathway) was dominated. This study developed a novel CuO-Fe<sub>2</sub>O<sub>3</sub>-modified Ni foam with a superior PMS activation performance, a high stability, and a recoverability for eliminating refractory organic pollutants.